МЕГАГРАНТЫ

Лаборатория фотоактивных нанокомпозитных материалов

О лаборатории

Лаборатория создана в рамках гранта Правительства Российской Федерации, выделенного на конкурсной основе для государственной поддержки научных исследований, проводимых под руководством ведущих ученых в российских образовательных учреждениях высшего профессионального образования (постановление правительства №220 от 9 апреля 2010 года).

Ссылка на сайт лаборатории

№ договора:
14.Z50.31.0016

Наименование ВУЗа:
ФГБОУ ВПО  "Санкт-Петербургский государственный университет"

Области научных исследований:
Химия

Цель проекта:
Создание крупного международного центра исследований фотоактивных нанокомпозитных материалов (ФНМ).

Задачи проекта:

— Исследование механизмов фотовозбуждения нанокомпозитных фотоактивных материалов.
— Разработка предложений по методам создания фотоактивных материалов первого и второго поколений и нанопокрытий на их основе с улучшенными функциональными характеристиками.
— Исследование фотопроцессов на поверхности нанопокрытий: гидрофильность, фотокаталитическая активность, бактерицидное действие.
— Развитие методов тестирования и характеризации функциональных параметров фотоактивных материалов.

 

Ведущий учёный

Bahnemann1 

ФИО: Бахнеманн Детлеф Вернер

 

Ученые степень и звание:
Доктор философии, Профессор

Занимаемая должность:
ГЛАВА ИССЛЕДОВАТЕЛЬСКОГО ЦЕНТРА ФОТОКАТАЛИЗА И НАНОТЕХНОЛОГИЙ

Области научных интересов:

Гетерогенный фотокатализ. Новые фотоактивныематериалы. Преобразование солнечной энергии. Фотосинтез. Экологически дружественная химия.

Научное признание:

Председатель Германского комитета по стандартизации (DIN)
«Фотокатализ».
Член Европейского комитета по стандартизации (CEN) «Фотокатализ».
Член Международного комитета по стандартизации (ISO) «Фотокатализ».
Почетный профессор:
• Robert Gordon University в Абердине (Великобритания);
• Xinjiang Technical Institute of Physics and Chemistry (КНР);
• Mahatma Gandhi University (Индия).
Участник редколлегий международных журналов Journal of Advanced Oxidation Technologies и International Journal of Photoenergy.

1. M. Bonifaciç, H. Möckel, D. Bahnemann, K.-D. Asmus “Formation of Positive Ions and Other Primary Species in the Oxidation of Sulphides by Hydroxyl Radicals” J. Chem. Soc., Perkin Trans 2 (1975) 675 - 685 DOI: 10.1039/P29750000675

2. D. Bahnemann, K.-D. Asmus “Formation of a Sulphur - Sulphur Bridged Radical Cation During the Oxidation of 1,4 - Dithian by Hydroxyl Radicals” J. Chem. Soc., Chem. Commun. (1975) 238-239 DOI: 10.1039/c39750 000238

3. K.-D. Asmus, D. Bahnemann, M. Bonifaciç, H. A. Gillis “Free Radical Oxidation of Organic Sulphur Compounds in Aqueous Solution” Faraday Disc. Chem. Soc. 63 (1978) 213 - 225 DOI: 10.1039/DC9776300213

4. K. Schäfer, M. Bonifaciç, D. Bahnemann, K.-D. Asmus “Addition of Oxygen to Organic Sulfur Radicals” J. Phys. Chem. 82 (1978) 2777-2780 DOI:10.1021/j100515a005

5. D. Bahnemann, H. Basaga, J. R. Dunlop, A. J. Searle, R. L. Willson “Metronidazole (Flagyl), Misonidazole (Ro 07-0582), Iron, Zinc, and Sulphur Compounds in Cancer therapy” Br. J. Cancer 37, Suppl. III (1978) 16-19 DOI/PMCID: PMC2149407

6. K.-D. Asmus, D. Bahnemann, H. Basaga, J. Dunlop, J. S. Mahood, J. E. Packer, A. J. Searle, T. F. Slater, R. L. Willson, B. Wolfenden “Free Radical Cascades and the Interaction of Radiosensitizers and Radioprotectors” Brit. J. Radiology 52 (1979) 600-601 ISSN: 0007-1285

Результаты исследований

V.N. Kuznetsov, A.V. Emeline, N.I. Glazkova, R.V. Mikhaylov, N. Serpone,’ Real-time in situ monitoring of optical absorption changes in visible-light-active TiO2 under light irradiation and temperature-programmed annealing‘, J. Phys. Chem. C 118 (2014) 27583.
F. M. Atitar, A.A. Ismail, S.A. Al-Sayari, D. Bahnemann, D. Afanasev, A.V. Emeline, ‘Mesoporous TiO2 nanocrystals as efficient photocatalysts: Impact of calcination temperature and phase transformation on photocatalytic performance‘, Chem. Eng. J. 264 (2015) 417.
R. Belykh, M. Maevskaya, I. Krauklis, and A. Tsyganenko, ‘Linkage isomerism of CO adsorbed on alkali halides‘, J. Phys. Chem. A 119 (2015) 2363.
F. Sambale, F. Stahl, D. Bahnemann, and T. Scheper, ‘In vitro toxicological nanoparticle studies under flow exposure‘, J. Nanopart. Res. 17 (2015) 298.
H. Belhadj, A.Hakki, P.K.J. Robertson, and D.W. Bahnemann, ‘In situ ATR-FTIR study of H2O and D2O adsorption on TiO2 under UV irradiation‘, PCCP 17 (2015) 22940-22946.
A.N. Dobrotvorskaia, T.D. Kolomiitsova, S.N. Petrov , D.N. Shchepkin, KS. Smirnov, A.A. Tsyganenko, ‘Effect of resonance dipole–dipole interaction on spectra of adsorbed SF6 molecules‘, Spectrochim. Acta A 148 (2015) 271-279.
M. Curti, J. Schneider, D.W. Bahnemann, and C.B. Mendive, ‘Inverse opal photonic crystals as a strategy to improve photocatalysis: Underexplored questions’, J. Phys. Chem. Lett. 6 (2015) 3903-3910.
E.S. Artemyeva, D.S. Barinov, F.M. Atitar, A.A. Murashkina, A.V. Emeline, N. Serpone, ‘Luminescence of photoactivated pristine and Cr-doped MgAl2O4 spinel‘, Chem. Phys. Lett. 626 (2015) 6.
A.V. Rudakova, U.G. Oparicheva, A.E. Grishina, M.V. Maevskaya, A.V. Emeline, and D.W. Bahnemann, ‘Dependences of ZnO photoinduced hydrophilic conversion on light intensity and wavelengths’, J. Phys. Chem. C 119 (2015) 9824.
N.I. Glazkova, R.V. Mikhaylov, and V.N. Kuznetsov, ‘Spectra of thermoprogrammed annealing of photoinduced color centers‘, Tech. Phys. Lett. 41 (2015) 389.
J.Freitag, A. Domínguez, T.A. Niehaus, A. Hülsewig, R. Dillert, T. Frauenheim, and D.W. Bahnemann, ‘Nitrogen (II) oxide charge transfer complexes on TiO2: A new source for visible-light activity‘, J. Phys. Chem. C 119 (2015) 4488.
M.G. Ahmed, T.A. Kandiel, A.Y. Ahmed, I. Kretschmer, F. Rashwan, and D. Bahnemann, ‘Enhanced photoelectrochemical water oxidation on nanostructured hematite photoanodes via p-CaFe2O4/n-Fe2O3 heterojunction formation‘, J. Phys. Chem. C 119 (2015) 5864.
J.H. Pan, C. Shen, I. Ivanova, N. Zhou, X. Wang, W.C. Tan, Q.-H. Xu, D.W. Bahnemann, and Q. Wang, ‘Self-template synthesis of porous perovskite titanate solid and hollow submicrospheres for photocatalytic oxygen evolution and mesoscopic solar cells‘, Appl. Mater. Interfaces 7 (2015) 14859.
S. Horikoshi, H. Tsutsumi, H. Matsuzaki, A. Furube, A.V. Emeline and N.Serpone, ‘In situ picosecond transient diffuse reflectance spectroscopy of opaque TiO2 systems under microwave irradiation and influence of oxygen vacancies on the UV-driven/microwave-assisted TiO2 photocatalysis’, J. Mater. Chem. C 3 (2015), 5958.
A.A. Murashkina, P.D. Murzin, A.V. Rudakova, V.K. Ryabchuk, A.V. Emeline, and D.W. Bahnemann, ‘Influence of the dopant concentration on the photocatalytic activity: Al-doped TiO2‘, J. Phys. Chem. C 119 (2015) 24695.
R. Kevorkyants, M.N. Sboev, Yu.V. Chizhov, ‘DFT study of molecular hydrogen interaction with photoexcited TiO2 surface: Nanocluster model‘, Chem. Phys. Lett. 639 (2015) 225.
J. Schneider, K. Nikitin, M. Wark, D.W. Bahnemanna and R. Marschall, ‘Improved charge carrier separation in barium tantalate composites investigated by laser flash photolysis‘, PCCP 18 (2016) 10719.
J. Sivanadanam, P. Ganesan, P. Gao, Md.K. Nazeeruddin, A. Emeline, D. Bahnemann and R. Rajalingam, ‘Impact of strength and size of donors on the optoelectronic properties of D–pi–A sensitizers‘, RSC Adv. 6 (2016) 37347.
A.V. Rudakova, U.G. Oparicheva, A.E. Grishina, A.A. Murashkina, A.V. Emeline, D.W. Bahnemann, ‘Photoinduced hydrophilic conversion of hydrated ZnO surfaces’, J. of Colloid and Interface Sci. 466 (2016) 452.
R. Kevorkyants, Yu.V. Chizhov, ‘The structure and aromaticity of 1,4 and 1,5 dihydro diazocine, dioxocine, hydro oxazocine: ab initio CCSD(T) singlet potential energy surface study‘, Tetrahedron Lett. 57 (2016) 340.
K.I. Reshetova, I.V. Krauklis, S.V. Litke, A.Yu. Ershov, Yu.V. Chizhov, ‘Spectroscopy and quantum-chemical calculations of nitro-bis-bipyridil complexes of ruthenium(II) with 4-substituted pyridine ligands‘, Opt. Spektrosk. 120 (2016) 566-574.
P.D. Murzin, R.G. Novikov, A.A. Tsyganenko, ‘Distortions in IR spectra related to the registration conditions: I. The influence of the reflection from interfaces‘, Opt. Spektrosk. 121 (2016) 10-17.
R.Kevorkyants, A.V.Rudakova, Yu.V.Chizhov, K.M.Bulanin, ‘The origin of 1560 cm-1 band in experimental IR spectra of water adsorbed on TiO2 surface: Ab initio assessment‘, Chem. Phys. Lett. 662 (2016) 97-101.
V.N.Kuznetsov, N.I.Glazkova, R.V.Mikhaylov and N.Serpone. ‘In situ study of photo- and thermo-induced color centers in photochromic rutile TiO2 in the temperature range 90–720 K‘, Photochem. Photobiol. Sci. 15 (2016) 1289–1298.
J. Schneider, K. Nikitin, R. Dillert, and D.W. Bahnemann, ‘Laser-flash-photolysis-spectroscopy: A nondestructive method ?‘, Faraday Discuss. (2016).
N. Serpone, A.V. Emeline, V.K. Ryabchuk, V.N. Kuznetsov, Yu.M. Artem’ev, and S. Horikoshi, ‘Why do hydrogen and oxygen yields from semiconductor-based photocatalyzed water splitting remain disappointingly low? Intrinsic and extrinsic factors impacting surface redox reactions‘, Energy Lett. 1 (2016) 931-948.
T.A. Kandiel, A. Ahmed, D. Bahnemann, ‘TiO2(B)/Anatase Heterostructure Nanofibers Decorated with Anatase Nanoparticles as Efficient Photocatalysts for Methanol Oxidation‘, J. Mol. Catal. A: Chem. 425 (2016) 55-60.
E. Friehs, Y. AlSalka, R. Jonczyk, A. Lavrentieva, A. Jochums, J.-G. Walter, F. Stahl, T. Scheper, D. Bahnemann, ‘Toxicity, phototoxicity and biocidal activity of nanoparticles employed in photocatalysis‘, J. Photochem. Photobiol. C: Photochem. rev. 29 (2016) 1-28.
A.V. Rudakova, M.V. Maevskaya, A.V. Emeline, and D.W. Bahnemann, ‘Light-Controlled ZrO2 Surface Hydrophilicity‘, Sci. Rep. 6 (2016) 34285.
F.H. Abdulrazzak, F.H. Hussein, A.F. Alkaim, I. Ivanova, A.V. Emeline, and D.W. Bahnemann, ‘Sonochemical/hydration–dehydration synthesis of Pt–TiO2 NPs/decorated carbon nanotubes with enhanced photocatalytic hydrogen production activity‘, Photochem. Photobiol. Sci. 15 (2016) 1347-1357.
N. Pugazhenthiran, K. Kaviyarasan, T. Sivasankar, A. Emeline, D. Bahnemann, R.V. Mangalaraja, S. Anandan, ‘Sonochemical synthesis of porous NiTiO3 nanorods for photocatalytic degradation of ceftiofur sodium‘, Ultrason. Sonochem. 35 (2016) 342-350.
V.K. Ryabchuk, V.N. Kuznetsov, A.V. Emeline, Yu.M. Artem’ev, G.V. Kataeva, S.Horikoshi, and N.Serpone, ‘Water Will Be the Coal of the Future—The Untamed Dream of Jules Verne for a Solar Fuel‘, Molecules 21 (2016) 1638.
R.V. Mikhaylov, N.I. Glazkova, K.V. Nikitin, ‘Photostimulated oxygen isotope exchange between N18O and anatase TiO2 under light irradiation‘, J. Photochem. Photobiol. A: Chemistry 332 (2017) 554-561.
Р.В. Михайлов, Н.И. Глазкова, В.Н. Кузнецов, ‘Фото- и термоиндуцированные центры окраски в керамике TiO2‘, Письма в ЖТФ 43 (2017) 39-45.
R. Kevorkyants, M.N. Sboev, Yu.V. Chizhov, ‘Ab initio R1 mechanism of photostimulated oxygen isotope exchange reaction on a defect TiO2 surface: The case of terminal oxygen atom exchange‘, Appl. Surf. Sci. 403 (2017) 342–346.
H. Belhadj, S. Melchers, P.K.J. Robertson, D.W. Bahnemann, ‘Pathways of the photocatalytic reaction of acetate in H2O and D2O: A combined EPR and ATR-FTIR study‘, J. Catal. XX (2017) XX-YY.


A.V. Emeline, V.K. Ryabchuk, V.N. Kuznetsov, N. Serpone, ‘Interplay between physical and chemical events in photoprocesses in heterogeneous systems‘, in ‘Photocatalysis : Fundamentals and Perspectives’, RSC Energy and Environment Series 2016.


8-th European Meeting on Solar Chemistry and Photocatalysis, 25/06/2014 — 28/06/2014, Thessaloniki, Greece

A.V. Emeline, A.V. Rudakova, A.A. Murashkina, K.V. Nikitin, U.G. Oparicheva, A.Ye. Grishina, ‘Effect of surface hydrating on superhydrophilic conversion of ZnO and TiO2 surfaces‘.
N.I. Glazkova, A.V. Emeline, V.N. Kuznetsov, R.V. Mikhaylov, V.K. Ryabchuk, N. Serpone, ‘Solar absorption of titania thermochemically fabricated from titanium and its alloys. UV and visible light induced photochromism of yellow titania‘.
N.I. Glazkova, V.N. Kuznetsov, R.V. Mikhaylov, N. Serpone, ‘Novel accessory for the cary eclipse fluorescence spectrophotometer for kinetic studies of the photophysical properties in photochromic materials‘.
A.A. Murashkina, N.I. Glazkova, A.V. Rudakova, V.K. Ryabchuk, A.V. Emeline, ‘Visible absorption spectra and photoactivity of Al-doped titania’.
D.S. Afanasev, A.V. Emeline, V.K. Ryabchuk, ‘Characteristics and photocatalytic activity of N-doped TiO2 prepared by different techniques‘.
K.V. Nikitin, A.V. Emeline, L.L. Shaytanov, and V.K. Ryabchuk, ‘Effect of fluorine-doping on spectral characteristics and photoactivity of titania‘.
E.S. Artemyeva, A.V. Emeline, D.W. Bahnemann, M.F. Atitar., D.S. Barinov, ‘Luminescence studies of photoactivated surface of pristine and Cr-doped MgAl2O4 spinel‘.

10-th International Conference on Physico-chemical problems of renewable energy, 30/06/14 — 02/07/14, Chernogolovka, Russia

A.A.Murashkina, A.V. Rudakova, N.I. Glazkova, V.K. Ryabchuk, and A.V. Emelin, ‘Electrochemical studies of photoprocesses on thin-film TiO2 electrodes‘.

20-th International Conference on Photochemical Conversion and Storage of Solar Energy, 27/07/14 – 01/08/14, Berlin, Germany

E.S. Artemyeva , A.V. Emeline , M.F. Atitar, ‘Luminescence of pristine and Cr-doped MgAl2O4 spinel induced by hydrogen chemisorption‘.
A.V. Rudakova, U.G. Oparicheva, A.E. Grishina, A.V. Emeline, ‘TiO2 and ZnO thin layers: Comparison of hydrophilic behavior‘.
A.V. Emeline, ‘Interplay between physical and chemical events in photoprocesses in heterogeneous systems‘.
K.V. Nikitin, A.V. Emeline, L. Shaytanov, and V.K. Ryabchuk, ‘Investigation of spectral characteristics and photoactivity of F-doped titania‘.
K.M. Bulanin, A.V. Emeline, A.V. Rudakova, ‘FT-IR study of the influence of UV-Vis irradiation on water layer on the TiO2 anatase powder surface‘.
N.I. Glazkova, A.V. Emeline, A.V. Rudakova, V.K. Ryabchuk, A.A. Murashkina, and R.V. Mikhaylov, ‘Effect of the dopant concentration on photoactivity of Al-doped TiO2 samples‘.
M.F. Atitar, D.W. Banemann, A.V. Emeline, ‘Effect of the calcination temperature on the photocatalytic and morphological properties of mesoporous TiO2 nanocrystals‘.
N.I. Glazkova, V.N. Kuznetsov, R.V. Mikhaylov, V.K. Ryabchuk, N. Serpone, ‘In situ optical study of UV/Vis- and thermo-stimulated effects in yellow titania‘.

2-nd Russian-German Workshop ‘Photoactive Nanocomposite Materials’, 5/10/14 — 10/10/14, Hannover, Germany

A.V. Emeline, ‘Interplay between physical and chemical events in photoprocesses in heterogeneous systems‘.
A.V. Rudakova, ‘Hydrophilic state conversion of the metal oxide surfaces: photoinduction‘.
U.G. Oparicheva, ‘The effect of alteration of hydrate multilayer on photoinduced hydrophilicity of ZnO nanofilms‘.
A.E. Grishina, ‘Spectral dependence of photoinduced hydrophilicity of ZnO nanofilms‘.
L.L. Shaytanov, ‘Effect of F-doping on photocatalytic activity of titania’.
A.S. Andreev, ‘Effect of the carbon doping on the oxygen vacancies formation in TiO2 anatase‘.
A.A. Murashkina, ‘Effect of the dopant concentration on photoactivity of Al-doped TiO2‘.
K.V. Nikitin, ‘Spectral dependencies of the quantum yield of photochemical processes on F-doped TiO2‘.
R.V. Mikhaylov, ‘Photostimulated oxygen isotope exchange and equilibration on TiO2 Degussa P25 under Vis light irradiation‘.
K.M. Bulanin, ‘Influence of UV-Vis irradiation on hydrated surfaces of TiO2 anatase: an FT-IR study‘.

5-th International Conference on Semiconductor Photochemistry, 27/07/15 — 31/07/15, St.Petersburg, Russia

D.W. Bahnemann, ‘Understanding charge transfer processes on metal oxide surfaces through laser flash photolysis analysis‘.
N.I. Glazkova, R.V. Mikhaylov, V.N. Kuznetsov, ‘Advanced diffuse reflectance spectroscopy for the study of charge separation in visible-light-active rutile titania‘.
A.V. Rudakova, U.G. Oparicheva, A.E. Grishina, M.V. Maevskaya, A.V. Emeline, D.W. Bahnemann, ‘Dependence of ZnO photoinduced hydrophilic conversion on light intensity and wavelengths‘.
M.N. Sboev, Yu.V. Chizhov, ‘DFT study of water interaction with photoexcited titanium dioxide surface: nanocluster model‘.
M.V. Maevskaya, A.V. Emeline, A.V. Rudakova, ‘Light-controllable hydrophilicity of ZrO2 nanocoatings‘.
A.V. Mayeuski, ‘Hydrogen photodissociation on metalorganic framework‘.
R.V. Mikhaylov, ‘Spectral features of photostimulated oxygen isotope exchange and NO adsorption on «selfsensitized» TiO2-x/TiO2 in Uv-Vis region‘.
A.A. Murashkina, R.V. Mikhaylov, A.V. Rudakova, K.V. Nikitin, V.K. Ryabchuk, A.V. Emeline, ‘Effect of Al-doping on the photoelectrochemical properties of TiO2‘.
P.D. Murzin, A.A. Murashkina, A.V. Emeline. A.V. Rudakova, K.M. Bulanin, ‘Photocatalytic activity of Al-doped TiO2‘.
K.V. Nikitin, A.V. Emeline, L.L. Shaytanov, and V.K. Ryabchuk, ‘Effect of fluorine-doping on spectral characteristics and photoactivity of titania‘.
D.A. Nosova, ‘Quantum-chemical calculations of the mefenamic acid‘.
U.G. Oparicheva, A.E. Grishina, A.A. Murashkina, A.V. Rudakova, A.V. Emeline, and D.W. Bahnemann, ‘Photoinduced hydrophilic conversion of hydrated ZnO surface‘.
A.E. Grishina, U.G. Oparicheva A.V. Emeline, ‘Synthesis, characterization and testing of doped ZnO‘.
K.I. Reshetova, ‘Quantum-chemical investigation of bisbipiridyl complex of ruthenium(II) with triphenylphosphine‘.
M.N. Sboev and Yu.V. Chizhov, ‘DFT study of molecular hydrogen interaction with photoexited defect titanium dioxide surface: nanocluster model‘.
L.L. Shaytanov, A.A. Murashkina, A.V. Rudakova , K.V. Nikitin, V.K. Ryabchuk, A.V. Emeline, ‘Effects of Al-doping on the photochromic properties of TiO2‘.
A.A. Murashkina, A.V. Emeline. A.V. Rudakova, K.V. Nikitin, R.V. Mikhaylov, V.K.Ryabchuk, ‘Fabrication and photoelectrochemical investigation of TiO2 nanotubes/WO3 nanoparticles/TiO2 heterostructure‘.

3-rd Russian-German Workshop ‘Photoactive Nanocomposite Materials’, 15/06/15 — 19/06/15, St.Petersburg, Russia

D.W. Bahnemann, ‘Good vs. bad practices in photocatalytic investigations‘.
A.S. Andreev, ‘Theoretical approaches to excited-state-related phenomena in TiO2‘.
N.I. Glazkova, ‘Separation of charge carriers photogenerated in yellow rutile as seen by advanced diffuse reflectance spectroscopy‘.
A.V. Rudakova, ‘Photoinduced wettability of solids‘.
K.M. Bulanin, ‘Vibrational spectroscopy of water molecules on TiO2 surface‘.
R.Belykh, ‘Hydrogenation of CO2 into methane on zeolite-supported Ni catalyst‘.
R.V. Mikhaylov, ‘Photostimulated interaction of simple molecules with TiO2 surface‘.
A.V. Mayeuski, ‘Metal-organic frameworks: Perspectives for photocatalysis‘.

XII-th European Congress on Catalysis, 30/08/15 — 04/09/15, Kazan, Russia

P.D. Murzin, ‘Photocatalytic activity of Al- doped TiO2‘.

227-th Electrochemical Society Meeting, 24/05/15 — 28/05/15, Chicago, USA

D.W. Bahnemann, ‘Concerning the role of sacrificial reagents in photocatalytic water splitting systems: A critical assessmen‘.

1-st International Solar Fuels Conference, 26/04/15 — 01/05/15, Uppsala, Sweden

D.W. Bahnemann, ‘Concerning the role of sacrificial reagents in photocatalytic water splitting systems: A critical assessmen‘.

1-st International Water Nexus Conference 2015: Catalysis for Water Purification, 28/10/15 — 30/10/15, Daegu, South Korea

D.W. Bahnemann, ‘Solar wastewater treatment‘.

Back to top